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Amount of heat required to change the temperature of one unit of amount of matter under a constant pressure  by one unit of temperature:

c_V = \frac{C_V}{\nu} = \frac{1}{\nu} \cdot \left( \frac{\delta Q}{\delta T} \right)_P
SymbolDimensionSI unitsOil metric unitsOil field units

c_V

M L2 T−2 Θ−1J/(molK)J/(molK)

 BTU/(mol°R)


It is a
material property and properly tabulated for the vast majority of materials.

The Isochoric molar heat capacity is related to Isobaric specific heat capacity  c_{Pm} and Volumetric Heat Capacity  c_{Pv} as:

(1) c_V = M \cdot c_{Vm}
(2) c_V = V_m \cdot c_{Vv}

where

M

molar mass of the substance 

V_m

molar volume of the substance 


The Isochoric molar heat capacity of the mixture in thermodynamic equilibrium follows the simple mixing rule:

(3) c_V = \sum_i \, x_i \, c_{V \, i}

where

x_i

mole fraction of the  i-th mixture component, subjected to \sum_i x_i= 1

c_{V\, i}

isochoric molar heat capacity of the  i-th mixture component

See also


Physics / Thermodynamics / Thermodynamic process Heat Transfer / Heat Capacity / Molar Heat Capacity

Isobaric molar heat capacity (cP) ]

Basic Petroleum Rock and Fluid Properties Handbook ]


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