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Explicit Z-factor correlation @model for the natural gas in the wide range of pseudo-reduced temperature  1.05 \leq T_{pr} \leq 3 and pseudo-reduced pressure  0.2 \leq P_{pr} \leq 15:

(1) Z = \frac{D \cdot P_{pr} \cdot (1+ y + y^2 - y^3)}{(D \cdot P_{pr} + E \cdot y^2 - F \cdot y^G)(1-y)^3}
(2) y = \frac{D \cdot P_{pr} }{Z^*}
(3) Z^* = \frac{1+A^2}{C} - \frac{A^2 B}{C^3}
(4) A=a_1 \, t \, \exp \left[ a_2 \, (1-t)^2 \right] \, p_{pr}
(5) B=a_3 \, t + a_4 \, t^2 + a_5\, t^6 \, p^6_{pr}
(6) C= a_9 + a_8 \, t \, p_{pr} + a_7 \, t^2 \, p^2_{pr} + a_6 \, t^3 \, p^3_{pr}
(7) D=a_{10} \, t \, \exp \left[ a_{11} (1-t)^2 \right]
(8) E=a_{12}\,t +a_{13}\,t^2 + a_{14}\,t^3
(9) F= a_{15}\,t +a_{16}\,t^2 + a_{17}\,t^3
(10) G=a_{18} + a_{19} t
(11) t= \frac{1}{T_{pr}}

where

Z

Z-factor

T

fluid temperature 

T_{pr} = T/T_{pc}

pseudo-reduced temperature 
(or reduced temperature  T_{r} in case of pure substances)

T_{pc}

 pseudo-critical temperature 
(or critical temperature  T_{c} in case of pure substances)

P

fluid pressure

P_{pr} = P/P_{pc}

pseudo-reduced pressure 
(or reduced pressure  P_{r} in case of pure substances)

P_{pc}

 pseudo-critical pressure 
(or critical pressure  P_{c} in case of pure substances)

and

a_1=0.317842

a_2=0.382216

a_3=-7.768354

a_4=14.290531

a_5=0.000002

a_6=-0.004693

a_7=0.096254

a_8=0.166720

a_9=0.966910

a_{10}=0.063069

a_{11}=-1.966847

a_{12}=21.0581

a_{13}=-27.0246

a_{14}=16.23

a_{15}=207.783

a_{16}=-488.161

a_{17}=176.29

a_{18}=1.88453

a_{19}=3.05921




The accuracy of the Kareem Z-factor Correlation @model within the stated above temperature-pressure range is given below:

Maximum Absolute Error0.0270Coefficient of Regression0.99972Maximum Percentage Error5.9976 %Average Percentage Error0.4379 %

See also


Natural Science / Physics /Thermodynamics / Z-factor / Z-factor Correlations @model

Pseudo-Critical Point Correlations @model ]

Reference


Lateef A. Kareem, et al, New explicit correlation for the compressibility factor of natural gas: linearized z-factor isotherms, J Petrol Explor Prod Technol (2016) 6:481–492, DOI 10.1007/s13202-015-0209-3







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