@wikipedia


Synonym
: Heat Capacity Ratio (γ)Adiabatic Index (γ) = Isentropic expansion factor (κ) = Isentropic exponent (κ)


Ratio between Isobaric heat capacity  
 and Isochoric heat capacity :

\gamma = \frac{C_P}{C_V}

Since  is the ratio it can be equivalently represented by intensive properties:


\gamma = \frac{c_P}{c_V} = \frac{c_{Pm}}{c_{Vm}}= \frac{c_{Pv}}{c_{Vv}}

where

Isobaric specific heat capacity

Isobaric volumetric heat capacity

Isochoric molar heat capacity

Isochoric specific heat capacity

Isochoric volumetric heat capacity


The Heat Capacity Ratio can be equivalently represented as ratio of Isothermal Compressibility  and Isentropic Compressibility :

\gamma=\frac{c_P}{c_V}=\frac{\beta_T}{\beta_S}= \kappa

wich is often denoted as  and referred as Isentropic exponent.


The Heat Capacity Ratio for ideal gases is:

\gamma = 1 + \frac{2}{f}

where

number of molecular freedom degrees


Heat capacity ratio for various fluids [1]

TempFluidγ
TempFluidγ
TempFluidγ
−181 °CH21.597200 °CDry air1.39820 °CNO1.400
−76 °C1.453400 °C1.39320 °CN2O1.310
20 °C1.4101000 °C1.365−181 °CN21.470
100 °C1.40415 °C1.404
400 °C1.3870 °CCO21.31020 °CCl21.340
1000 °C1.35820 °C1.300−115 °CCH41.410
2000 °C1.318100 °C1.281−74 °C1.350
20 °CHe1.660400 °C1.23520 °C1.320
20 °CH2O1.3301000 °C1.19515 °CNH31.310
100 °C1.32420 °CCO1.40019 °CNe1.640
200 °C1.310−181 °CO21.45019 °CXe1.660
−180 °CAr1.760−76 °C1.41519 °CKr1.680
20 °C1.67020 °C1.40015 °CSO21.290
0 °CDry air1.403100 °C1.399360 °CHg1.670
20 °C1.400200 °C1.39715 °CC2H61.220
100 °C1.401400 °C1.39416 °CC3H81.130


In express analysis of
petroleum fluids (including liquid water and vapour) the Heat Capacity Ratio can be assumed .

See also


Physics / Thermodynamics / Thermodynamic process 

Mayer's relation ]

References


White, Frank M. (October 1998). Fluid Mechanics (4th ed.). New York: McGraw HillISBN 978-0-07-228192-7.