Equation of State for the Real Gas:
(1) | \rho(p, T) = \frac{1}{Z} \cdot \frac{M}{R} \cdot \frac{p}{T} |
where
\rho | Gas density | p | Gas pressure | M | Gas molar mass |
Z(T, p) | Compressibility factor | T | Gas temperature | R | Gas constant |
Despite the name it covers a lot of medium-density liquids as well.
Pure Substances
The Z-factor
Z(p, T) of pure substances is usually modelled through the reduced fluid properties
(T_r, p_r):
T_r = T/T_c | Reduced Temperature | T_c | Сritical temperature |
p_r = p/p_c | Reduced Pressure | p_c | Critical pressure |
Below is the list of the most popular Real Gas EOS @models:
Peng–Robinson-Stryjek-Vera (PRSV) EOS @model |
Peng–Robinson (PR) EOS @model |
Soave-Redlich-Kwong (SRK) EOS @model |
Fluid Mixtures
The Z-factor
Z(p, T) of fluid mixtures is usually modelled through the pseudo-reduced fluid properties
(T_{pr}, p_{pr}):
T_{pr} = T/T_{pc} | Reduced Temperature | T_{pc} | Pseudo-critical temperature |
p_{pr} = p/p_{pc} | Reduced Pressure | p_{pc} | Pseudo-critical pressure |
See Z-factor Correlations @model for the charts, implicit and explicit empirical correlations on fluid mixture Z-factor Z(T_{pr}, p_{pr}).
See also
Natural Science / Physics / Thermodynamics / Thermodynamic system / Equation of State / Real Gas
[ Ideal Gas EOS @model ][ Soave-Redlich-Kwong (SRK) EOS @model ][ Peng–Robinson EOS @model ]
[ Reduced Fluid Properties ][ Pseudo-Reduced Fluid Properties ]