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@wikipedia


Synonyms
Compressibility factorZ-factor

Disclaimer: Not to be confused with Compressibility 

LaTeX Math Inline
bodyc
.

Dimensionless multiplier describing the deviation of a fluid density from ideal gas estimate under the same pressure & temperature conditions:

LaTeX Math Block
anchorZ
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Z = \frac{p  \, V_m}{R \, T} = \frac{p}{\rho} \cdot \frac{M}{R \, T}

where

LaTeX Math Inline
bodyp

fluidpressure

LaTeX Math Inline
bodyV_m = V/\nu

fluid molar volume

LaTeX Math Inline
bodyT

fluidtemperature

LaTeX Math Inline
bodyV

fluidvolume

LaTeX Math Inline
body\rho

fluid density

LaTeX Math Inline
body\nu

amount of substance

LaTeX Math Inline
bodyR

gas constant

LaTeX Math Inline
bodyM

molar mass of a fluid


Alternatively Z-factor can be expressed through the dynamic fluid properties at reference conditions as:

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anchorP7SN4
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Z(T, p) = Z^{\circ} \cdot \frac{\rho^{\circ} \, T^{\circ}}{p^{\circ}} \cdot \frac{p}{\rho(T, p) \, T} 

where 

LaTeX Math Inline
body--uriencoded--()%5e%7B\circ%7D
 means reference conditions, usually Standard Conditions (STP).


Z-factor can be used to calculate fluid density 

LaTeX Math Inline
body\rho
 and Formation Volume Factor (FVF) 
LaTeX Math Inline
bodyB
as:

LaTeX Math Block
anchorrho
alignmentleft
\rho(T, p) = \rho^{\circ} \cdot \frac{Z^{\circ} \, T^{\circ}}{p^{\circ}} \cdot \frac{p}{Z(T, p) \, T} 
LaTeX Math Block
anchorrho
alignmentleft
B(T, p) = \frac{\rho^{\circ}}{\rho(T, p)} =  \frac{p^{\circ} }{Z^{\circ} \, T^{\circ}} \cdot \frac{Z(T, p) \, T}{p} 


Z-factor is related to fluid compressibility 

LaTeX Math Inline
bodyc
as:

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anchorcZ
alignmentleft
c(p) = \frac{1}{p} - \frac{1}{Z} \frac{dZ}{dp}
LaTeX Math Block
anchorZ_c
alignmentleft
Z(p) = Z_0 \cdot \frac{p}{p_0} \cdot \exp \left[ - \int_{p_0}^p c(p) dp  \right]



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LaTeX Math Block
anchorcZder
alignmentleft
c = \frac{1}{\rho} \frac{d\rho}{dp}  = \frac{d \ln \rho}{dp} =  \frac{d }{dp} \left(  \ln  \left(\frac{p}{Z} \right)  \right) = \frac{Z}{p} \cdot \frac{d }{dp} \left(\frac{p}{Z} \right) = \frac{Z}{p} \cdot \left( \frac{1}{Z} + p \cdot \frac{d }{dp} \left( \frac{1}{Z} \right)   \right) = \frac{1}{p}  - \frac{1}{Z} \frac{dZ}{dp}

Rewriting 

LaTeX Math Block Reference
anchorcZ
:

LaTeX Math Block
anchorcZ
alignmentleft
\frac{d \ln Z}{dp} = \frac{1}{p} - c(p) \rightarrow \ln \frac{Z}{Z_0} = \ln \frac{p}{p_0} - \int_{p_0}^p c(p) \, dp

which arrives to 

LaTeX Math Block Reference
anchorZ_c
.


The
Z-factor value is trending towards unit value (

LaTeX Math Inline
bodyZ \rightarrow 1
) for incompressible fluids and linear pressure dependence (
LaTeX Math Inline
bodyZ \rightarrow a \cdot p
) for strongly compressible fluids.

Modelling Z-factor 

LaTeX Math Inline
bodyZ(T,p)
as a function of fluidpressure 
LaTeX Math Inline
bodyp
 and temperature 
LaTeX Math Inline
bodyT
 is based on Equation of State.


There is also a good number of explicit Z-factor Correlations @models.


See also


Natural Science / Physics / Thermodynamics / Equation of State

[ Compressibility ]Fluid Compressibility ][ Gas compressibility ]

References


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Lateef A. Kareem, New explicit correlation for the compressibility factor of natural gas, 2016