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Both
and LaTeX Math Inline body C_P
are proportional to the amount of chemical substance involved in a heat transfer process and as such are not the material properties. LaTeX Math Inline body C_V
The ratio
is called a Heat Capacity Ratio (γ) or Adiabatic Index (γ) or Isentropic expansion factor (κ) and is a material property. LaTeX Math Inline body \gamma = C_P/C_V
Based on Mayer's relation the Isobaric heat capacity is always greater than Isochoric heat capacity:
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