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The rock volume 

LaTeX Math Inline
body\Omega_r
 is split into three major components: pore volume 
LaTeX Math Inline
body\Omega_e
shale volume 
LaTeX Math Inline
body\Omega_{sh}
 and rock martix 
LaTeX Math Inline
body\Omega_m
:

LaTeX Math Block
anchorOmega_R
alignmentleft
\Omega_r = \Omega_e +\Omega_{sh} + \Omega_m

The usual practice is to use relative volumes:

LaTeX Math Block
anchorOmega_R
alignmentleft
\phi_e = \frac{\Omega_e}{\Omega_r}, \quad V_{sh} = \frac{\Omega_{sh}}{\Omega_r}, \quad V_m = \frac{\Omega_m}{\Omega_r}

which are measured in V/V units (or fracs) and honor the following constraint:

LaTeX Math Block
anchorV_R
alignmentleft
\phi_e +V_{sh} + V_m = 1

Anchor
phie
phie

The relative pore volume 

LaTeX Math Inline
body\phi_e
 is also called effective porosity (PHIE) and contains free and connate fluids (water, oil , gas).The log name is PHIE.


It corresponds to air porosity of the dried laboratory cores: 

LaTeX Math Inline
body\phi_e = V_{\rm air \, core}


The relative shale volume 

LaTeX Math Inline
bodyV_{sh}
 is called shaliness and contains three major components: silt  
LaTeX Math Inline
bodyV_{\rm silt}
clay 
LaTeX Math Inline
bodyV_c
 and clay bound water 
LaTeX Math Inline
bodyV_{\rm cbw}
:

LaTeX Math Block
anchorV_sh
alignmentleft
V_{sh} = V_{\rm silt} + V_c + V_{\rm cbw}

The log name is VSH.


The clay bound water 

LaTeX Math Inline
bodyV_{\rm cbw}
 is usually measured as the fraction of shale volume:


LaTeX Math Block
anchorV_sh
alignmentleft
V_{\rm cbw} = s_{\rm cbw} \cdot V_{sh} 

where 

LaTeX Math Inline
bodys_{\rm cbw}
 is called bulk volume water of shale (BVWSH).


The total porosity is defined as the sum of effective porosity 

LaTeX Math Inline
body\phi_e
 and clay bound water 
LaTeX Math Inline
bodyV_{\rm cbw}
:

LaTeX Math Block
anchorphi_t
alignmentleft
\phi_t  = \phi_e + V_{\rm cbw} = \phi_e + s_{\rm cbw} V_{sh}

The log name is PHIT.


The term total porosity is more of a misnomer as it actually does not represent a pore volume for free flow as the clay bound water is essential part of the rock solids. 

Nevertheles, the total porosity property has been adopted by petrophysics as a part of interpretation workflow where the intermediate value of total porosity from various sensors leads not only to effective porosity but also to  lithofacies analysis.


The effective porosity  is not a final measure of the volume available for flow.

It includes the unconnected pores which do not contribute to flow:

LaTeX Math Block
anchorphi_t
alignmentleft
\phi_e  = \phi_{\rm open} + \phi_{\rm closed}


Besides the connected effective pore volume

LaTeX Math Inline
body\phi_{\rm open}
includes the connate fluids which may be not flowing in the practical range of subsurface temperatures, pressure gradients and sweeping agents:

LaTeX Math Block
anchorphi_t
alignmentleft
\phi_{\rm open} = \phi_{\rm free} + \phi_{\rm connate}


Finally, the pore volume available for flow is represented by the following formula: 

LaTeX Math Block
anchorphi_t
alignmentleft
\phi_{\rm flow} = \phi_e \cdot (1 - s_{\rm connate})

where 


LaTeX Math Block
alignmentleft
s_{\rm connate}=\frac{\phi_{\rm connate}}{\phi_{\rm open}}



a fraction of pore volume, occupied by connate fluid (usually water or oil) and estimated in laboratory Special Core Analysis (SCAL)


As one may expect the

LaTeX Math Inline
body\phi_{\rm flow}
value has the best correlation with permeability.

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