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Implicit Z-factor correlation @model for the natural gas in the wide range of pseudo-reduced temperature  1.0 < T_{pr} \leq 3.0 and pseudo-reduced pressure  0.2 \leq P_{pr} \leq 30

and also a specific range of 0.7 < T_{pr} \leq 1.0 and P_{pr} < 1.0:

(1) Z = \frac{0.27 \, P_{pr}}{y \, T_{pr}}
(2) 1 + T_1 \, y + T_2 \, y^2 + T_3 \, y^5 + T_4 \, y^2 \, (1+ A_{11} \, y^2) \, \exp (- A_{11} \, y^2) - \frac{T_5}{y} = 0

(3) T_1 = A_1 + \frac{A_2}{T_{pr}} + \frac{A_3}{T_{pr}^3} + \frac{A_4}{T_{pr}^4} + \frac{A_5}{T_{pr}^5}
(4) T_2 = A_6 + \frac{A_7}{T_{pr}} + \frac{A_8}{T_{pr}^2}
(5) T_3 = - A_9 \cdot \left[ \frac{A_7}{T_{pr}} + \frac{A_8}{T_{pr}^2} \right]
(6) T_4 =\frac{A_{10}}{T_{pr}^3}
(7) T_5 = \frac{0.27 \, P_{pr} }{T_{pr}}

where

Z

Z-factor

T

fluid temperature 

T_{pr} = T/T_{pc}

pseudo-reduced temperature 
(or reduced temperature  T_{r} in case of pure substances)

T_{pc}

 pseudo-critical temperature 
(or critical temperature  T_{c} in case of pure substances)

P

fluid pressure

P_{pr} = P/P_{pc}

pseudo-reduced pressure 
(or reduced pressure  P_{r} in case of pure substances)

P_{pc}

 pseudo-critical pressure 
(or critical pressure  P_{c} in case of pure substances)

and

A_1 = 0.3265

A_2 = -1.070

A_3 = - 0.5339

A_4 = 0.01569

A_5 = - 0.05165

A_6 = 0.5475

A_7 = -0.7361

A_8 = 0.1844

A_9 = 0.1056

A_{10} = 0.6134

A_{11} = 0.7210


See also


Natural Science / Physics /Thermodynamics / Z-factor / Z-factor Correlations @model

Reference


Dranchuk, P.M., and H. Abou-Kassem. "Calculation of Z Factors For Natural Gases Using Equations of State." J Can Pet Technol 14 (1975): doi.org/10.2118/75-03-03


 








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