Peng–Robinson-Stryjek-Vera (PRSV) EOS @model

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One of the cubic equations of real gas state defining the Compressibility factor $\begin{array}{l}Z(p, T)\end{array}$ as a function of fluid pressure $\begin{array}{l}p\end{array}$ and fluid temperature $\begin{array}{l}T\end{array}$ :

(1)	$\begin{array}{l}\displaystyle Z^3 - (1-B) \, Z^2 +(A-2B-3B^2) \, Z -(AB-B^2-B^3) = 0\end{array}$

(2)	$\begin{array}{l}\displaystyle A= 0.45724 \cdot \alpha \cdot \frac{p_r}{T_r^2}\end{array}$

(3)	$\begin{array}{l}\displaystyle B=0.07780 \cdot \frac{p_r}{T_r}\end{array}$

(4)	$\begin{array}{l}\displaystyle \alpha = \left( 1 + \kappa \, (1-T_r^{0.5}) \right)^2\end{array}$

(5)	$\begin{array}{l}\displaystyle \kappa = \kappa_0 + \left[ \kappa_1 + \kappa_2 (\kappa_3 - T_r) (1-T_r^{0.5}) \right]\, (1+T_r^{0.5}) \, (0.7 - T_r)\end{array}$

(6)	$\begin{array}{l}\displaystyle \kappa_0 = 0.378893 + 1.4897153 \, \omega -0.17131848 \, \omega^2 +0.0196554 \, \omega^3\end{array}$

where

$\begin{array}{l}Z\end{array}$	Compressibility factor	$\begin{array}{l}p_c\end{array}$	Critical pressure
$\begin{array}{l}p\end{array}$	Fluid pressure	$\begin{array}{l}T_c\end{array}$	Сritical temperature
$\begin{array}{l}T\end{array}$	Fluid temperature	$\begin{array}{l}p_r = p/p_c\end{array}$	Reduced pressure
$\begin{array}{l}R\end{array}$	Gas constant	$\begin{array}{l}T_r = T/T_c\end{array}$	Reduced temperature
$\begin{array}{l}\omega\end{array}$	Acentric factor	$\begin{array}{l}\{ \kappa_1, \, \kappa_2, \, \kappa_3 \}\end{array}$	fitting parameters

Once compressibility Z-factor $\begin{array}{l}Z(p, T)\end{array}$ is known the fluid density $\begin{array}{l}\rho\end{array}$ can be calculated as:

(7)	$\begin{array}{l}\displaystyle \rho(p, T) = \frac{1}{Z(p,T)} \cdot \frac{M}{R} \cdot \frac{p}{T}\end{array}$

where

$\begin{array}{l}M\end{array}$

fluid molar mass

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Peng–Robinson-Stryjek-Vera (PRSV) EOS @model