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The simplest estimate  (also called Linear Blending Rule) of Pseudo-Critical Point 

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body--uriencoded--( T_%7Bpc%7D, \, pP_%7Bpc%7D )
 is the mole fraction weighted average of the critical temperature 
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body--uriencoded--\%7B T_%7Bc, i%7D \%7D
 and  critical pressure 
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body--uriencoded--\%7B pP_%7Bc, i%7D \%7D
 of fluid components (which are pure substances) :

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anchorppc
alignmentleft
pP_{pc} = \sum_i x_i \, pP_{c,i}

where

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bodyx_i

mole fraction of the 

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bodyi
-th mixture component

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body--uriencoded--T_%7Bc,i%7D

critical temperature of the 

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bodyi
-th mixture component

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body--uriencoded--pP_%7Bc,i%7D

critical pressure of the 

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bodyi
-th mixture component

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Pseudo-Critical Point (Tpc, pPpc) ][ Pseudo-Critical Temperature (Tpc) ][ Pseudo-Critical Pressure (Ppc)][ Pseudo-Critical Point Correlations @model ]

[ Critical Point (Tc, pPc) ][ Сritical Temperature  (Tc) ][ Critical Pressure (pPc) ]