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The simplest estimate  (also called Linear Blending Rule) of  of Pseudo-Critical Point 

LaTeX Math Inline
body--uriencoded--( T_%7Bpc%7D, \, p_%7Bpc%7D )
 is the mole fraction weighted average of the critical temperature 
LaTeX Math Inline
body--uriencoded--\%7B T_%7Bc, i%7D \%7D
 and  critical pressure 
LaTeX Math Inline
body--uriencoded--\%7B p_%7Bc, i%7D \%7D
 of fluid components (which are pure substances) :

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