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Fig. 1. Schematic PT diagram with Vapour Liquid Equilibrium and Pseudo-Critical Point (Tpc, ppc). |
The simplest estimate estimate (also called Linear Blending Rule) of Pseudo-Critical Point
is the mole fraction weighted average of the Сritical Temperature (Tc) and Critical Pressure (pc) of mixture components (which are pure substances) : LaTeX Math Inline body --uriencoded--( T_%7Bpc%7D, \, p_%7Bpc%7D )
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T_{pc} = \sum_i x_i \, T_{c,i} |
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| mole fraction of the | ||||||||
| critical temperature of the | ||||||||
| critical pressure of the |
There are other no-linear methods to blend the components to estimate the Pseudo-Critical Point but many engineering applications use Apart from
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In case the fluid composition is not known one can use some popular empirical Pseudo-Critical Point Correlations to assess the Pseudo-Critical Point.
See also
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Natural Science / Physics / Thermodynamics / Thermodynamic system
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[ Critical Point (Tc, pc) ][ Сritical Temperature Temperature (Tc) ][ Critical Pressure (pc) ]
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