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Synonym: Fluid Phase EquilibriumVapour Liquid Equilibrium (VLE)

A partial case of Phase Equilibrium with two fluid phases staying at Thermodynamic equilibrium.

In other words it's a
 state of thermodynamic equilibrium between the liquid and gas state of a Fluid Mixture. 


The 
PT Diagram for Pure Substance will see Vapour Liquid Equilibrium (VLE) as a set of points along a smooth curve ending up with a Critical Point  (T_c, p_c) (see Fig. 1).

The PT Diagram for Fluid Mixture will see Vapour Liquid Equilibrium (VLE) as a closed region (also called Vapour Liquid Envelope) bounded by Bubblepoint Curve and Dewpoint Curve with a junction at Pseudo-Critical Point  (T_{pc}, p_{pc}) (see Fig. 2).


Supercritical carbon dioxide - Wikipedia


Fig. 1. Schematic PT Diagram with Vapour Liquid Equilibrium curve and Critical Point.Fig. 2. Schematic PT Diagram with Vapour Liquid Envelope and Pseudo-Critical Point.

See also


Natural Science / Physics / Thermodynamics / Thermodynamic system / Thermodynamic equilibrium / Phase Equilibrium

State of matter ]Pure substance ] [ Mixtures ][ Fluid Mixtures ]Phase ]

Dewpoint Curve ][ Bubblepoint Curve ][ Vapour Liquid Envelope ]

[ Critical Point (Tc, Pc) ]Сritical Temperature Tc ] [ Critical Pressure (pc) ][ Cricondentherm ][ Cricondenbar ]



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